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Rajinikanth as 'Annaatthe' Kaalaiyaan |
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Keerthi Suresh as Thanga Meenakshi |
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Jagapati Babu as Udhav Palekar |
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Soori as Pachakili |
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Nayanthara as Pattamal |
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Meena as Mangayarkarasi |
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Khushboo as Angayarkanni |
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Bala as Arjun |
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Prakash Raj as Nattadurai |
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Abhimanyu Singh as Manoj Palekar |
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Vela Ramamoorthy as Kaalaiyan’s uncle |
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Pandiarajan as Angayarkanni’s husband |
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Livingston as Mangayarkarasi’s husband |
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Sathyan Sivakumar as Mangayarkarasi’s brother |
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Sathish as Angayarkanni’s brother |
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George Mariyan as Komberi Mookan |
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Redin Kingsley as Nattadurai's Brother In Law |
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Hrishikesh as A Potential Groom |
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Thavasi as Priest |
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Kabali Vishwanth as |
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Arjai as |
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Nadodigal Gopal as Kaalaiyan's Uncle |
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Kulappulli Leela as Kaalaiyaan’s grandmother |
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Billy Murali as Manoj Palekar's Henchman |
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Brana as |
| Sound | S. P. Balasubramaniam | Playback Singer |
| Production | Kabilan Chellaiah | Publicist |
| Art | Milan | Art Direction |
| Crew | Dhilip Subbarayan | Stunt Coordinator |
| Crew | Brinda | Choreographer |
| Crew | Prem Rakshith | Choreographer |
| Writing | Viveka | Lyricist |
| Writing | Mani Amudhavan | Lyricist |
| Costume & Make-Up | Anu Vardhan | Costume Design |
| Costume & Make-Up | Dhatsha Pillai | Costume Design |
| Costume & Make-Up | Shravya Varma | Costume Design |
| Costume & Make-Up | Anu Parthasarathy | Costume Design |
| Costume & Make-Up | Sangeetha | Costume Design |
| Production | D Ramesh Kuchirayar | Production Executive |
| Production | R S Suresh Maniyan | Production Executive |
| Production | Thandavakrishnan | Production Executive |
| Production | R. Anbazhagan | Production Executive |
| Camera | V. Sittrarasu | Still Photographer |
| Writing | Adhi Narayana | Co-Writer |
| Directing | R. Rajasekar | Co-Director |
| Crew | Riaz K. Ahmed | Public Relations |
| Sound | T. Udayakumar | Sound Designer |
| Editing | K. S. Rajasekaran | Colorist |
| Visual Effects | Harihara Suthan | VFX Supervisor |
| Writing | Savari Muthu | Dialogue |
| Writing | Siva | Dialogue |
| Editing | C.M.Elangovan | Assistant Editor |
| Writing | Thamarai | Lyricist |
| Writing | Yugabharathi | Lyricist |
| Writing | Arun Bharathi | Lyricist |
| Writing | Arivu | Lyricist |
| Visual Effects | Harihara Suthan | Visual Effects |
| Writing | Anthony Bhagyaraj | Dialogue |
| Sound | Sid Sriram | Playback Singer |
| Sound | Shreya Ghoshal | Playback Singer |
| Sound | Nakash Aziz | Playback Singer |
| Sound | Anthony Daasan | Playback Singer |
| Sound | Vandana Srinivasan | Playback Singer |
| Sound | Nochipatti Thirumoorthi | Playback Singer |
| Sound | Mukesh Mohamed | Playback Singer |
| Sound | Keezhakarai Samsutheen | Playback Singer |
| Sound | Arivu | Playback Singer |
| Sound | Rajinikanth | Playback Singer |
| Sound | K. S. Chithra | Playback Singer |
| Writing | Adhi Narayana | Story |
| Writing | Chandran Pachamuthu | Dialogue |
| Directing | Siva | Director |
| Production | Kalanithi Maran | Producer |
| Writing | Siva | Screenplay |
| Editing | Antony L. Ruben | Editor |
| Writing | Siva | Story |
| Camera | Vettri | Director of Photography |
| Sound | D. Imman | Original Music Composer |
